The Sexiest Moments from Gossip Girl (2007–2012): Blake Lively, Leighton Meester & More

From Blake Lively’s sultry fashion to Leighton Meester’s lingerie-filled scenes and Hilary Duff’s iconic threesome, revisit the steamiest moments from Gossip Girl’s original run.

by Laura

The Sexiest Moments from Gossip Girl (2007–2012): Blake Lively, Leighton Meester & More

Before Euphoria and Elite, there was Gossip Girl—the CW’s steamy teen drama that blended high fashion with even higher levels of scandal. Airing from 2007 to 2012, the show followed Manhattan’s elite prep schoolers as they navigated love, betrayal, and vicious social wars, all under the watchful eye of a mysterious blogger. But beyond the drama and designer wardrobes, Gossip Girl served up a generous helping of sultry, provocative moments that had fans glued to their screens. Let’s dive into the hottest highlights that made the series unforgettable.


Blake Lively as Serena van der Woodsen

Blake Lively was the ultimate Upper East Side “it” girl as Serena van der Woodsen—a tall, blonde bombshell with an effortless aura of sensuality. Whether she was walking through Central Park in designer heels or slipping into a barely-there bikini at a Hamptons pool party, Serena’s screen presence was magnetic.

Blake’s wardrobe alone made headlines: plunging necklines, curve-hugging gowns, silky sleepwear, and stylish lingerie that left just enough to the imagination. Even without nudity, Serena’s sex appeal was in full swing, and Blake Lively quickly became one of the most lusted-after stars of her era.

Blake Lively in Gossip Girl (2007-2012)


Leighton Meester as Blair Waldorf

On the opposite end of the seduction spectrum was Leighton Meester’s Blair Waldorf—a fierce, fashion-forward queen bee who mastered the art of elegant eroticism. While Serena brought the boho bombshell vibes, Blair was all about polished perfection and strategic sensuality.

From her corset scenes to her candlelit trysts with Chuck Bass, Blair’s romantic escapades were some of the most passionate in the series. Meester brought an undercurrent of dominance and control to Blair’s sexuality, making every kiss and glance drip with tension. Whether she was commanding the bedroom or plotting her next move, Blair always played it sexy, smart, and just a little wicked.

Leighton Meester in Gossip Girl (2007-2012)


Hilary Duff’s Threesome Twist

In a surprise casting choice that paid off big, Hilary Duff joined the cast for a mini-arc as Olivia Burke—a movie star looking for a taste of “normal” college life. Instead, she found herself in one of Gossip Girl’s most talked-about scenes: a steamy threesome with Dan (Penn Badgley) and Vanessa (Jessica Szohr).

For a show known for its PG-13 boundaries, this storyline pushed things further than fans expected. The scene didn’t go full HBO, but the makeout session, implied nudity, and slow, suggestive undressing lit up social media at the time. It was a bold, sexy move that showed Hilary Duff could heat up a scene just as well as anyone else.

Hilary Duff in Gossip Girl (2007-2012)


Jessica Szohr as Vanessa Abrams

Jessica Szohr’s Vanessa may have been the show’s bohemian outsider, but she had her share of spicy screen time—especially when she joined that infamous threesome. Often dressed in grungy-cool outfits, Vanessa’s understated sex appeal gave her a unique presence in a show dominated by glamor and glitz.

That bedroom rendezvous with Dan and Olivia wasn’t just a twist—it was a defining moment for her character. It added unexpected heat to Vanessa’s storyline and showed that even Gossip Girl’s “outsiders” could stir up major steamy drama.

Jessica Szohr in Gossip Girl (2007-2012)


Upper East Side Seduction

Though the show never showed nudity, Gossip Girl masterfully balanced teen drama with mature themes of sexuality and power. It played in the gray areas—suggestive scenes, smoldering tension, and endless fashion-forward stripteases. It was less about graphic visuals and more about the vibe—slow glances, whispered lines, and the simmering heat of secrets.


Final Thoughts:

From Blake Lively’s sultry beachwear to Leighton Meester’s boudoir-worthy wardrobe and Hilary Duff’s wild guest-star moment, Gossip Girl packed a whole lot of sexy into six seasons of scandal. These moments weren’t just hot—they were iconic, helping redefine CW’s image and cementing the series as a guilty pleasure for an entire generation.

Whether you’re revisiting the series or discovering it for the first time, these seductive scenes still hold up—and remain a glittering reminder that nobody does sexy scandal quite like the Upper East Side. XOXO.

All the images here appear courtesy of Mr. Skin.

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